Effect of Changing Anion on the Crystalline Structure, Crystal Structure, Hirschfield Surface, IR and NMR Spectroscopy of Organic Salts and Hybrid Compounds: C<sub>6</sub>H<sub>4</sub>(NH<sub>3</sub>)<sub>2</sub>Cl<sub>2</sub> (I), <i>β</i>-[C<sub>6</sub>H<sub>10</sub>N&…

Two organic-inorganic hybrid materials, C6H4(NH3)2∙Cl2 (I) and β-[C6H10N2]2ZnCl4 (II), have been synthesized by hydrothermal method. These two materials are one of the emerged as most brilliant components classes. extraordinary compounds synergistically combine desired physical properties both organic inorganic into a single compound offering possibility to achieve great improvement over time in terms science across various sectors. Their structures were determined XRD pattern investigations crystal X-ray diffraction. crystallized monoclinic system; C2/c space group. In structures, anionic-cationic entities interconnected hydrogen bonding contacts p-p Interaction forming three-dimensional networks. Intermolecular interactions investigated Hirshfeld surfaces four different chloride atoms (II) compared. The vibrational absorption bands identified infrared spectroscopy. also solid state13C NMR